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> Cum Sa Protejezi Figurinele, Informatii despre materiale: PVC, resin


jkno
post Jan 1 2009, 02:27 PM
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Differences in Plastics - ABS, PVC, Vinyl, Resin, Polystone


A while ago, I had posted an article on Anime Figurines Network on the difference between certain types of plastics. Today, I’ve decided to take that article, make modifications and clarifications on it, and post it here. This article will cover various plastics from PVC, to Resin, and their methods, properties and advantages.

Polyvinyl Chloride (PVC)
PVC is a softer plastic, that is typically tinted before being put into the mold. It’s easily paintable (no primer needed) and acrylic paint just typically sticks to it without much of a hitch. It’s relatively cheap plastic. Also, because of its soft properties, sculptors are able to get away with putting in more detail and awkward angles. The downside obviously, is it’s soft, there’s a high chance of leaning figures. PVC is also easily repairable and very durable. You can drop a PVC figure without much problem, and it takes a lot of deliberate strength to tear PVC apart. But at that same note, it is a lot weaker than ABS.

PVC can also be made into a very hard plastic (PVC pipes). This is based on the density of how much plastic is put into an area. They do this with some of the single-leg standing pose figures. By increasing the density and consistency, there is less chance of leaning.

PVC poses some health concerns to most people, and as a figure collector, it should concern you too. To get the soft consistency of PVC, plasticizers must be added to it. Fortunately, it would only be hazardous to you if you ingest the PVC somehow, either through eating, or sticking it in places you’re not supposed to. Hence, baby toys and adult sex toys are considered part of this category. On another note, the PVC manufacturing process produces a lot of dioxins which are environmentally unfriendly. The next time you purchase a PVC figure, be more selective to save the environment, money, space, and general other headaches later on. Some PVC can be recycled (if it has the number 3 on it). So if you’ve had it with that figure you own, and nobody wants to buy it, see if it can be recycled first! Chances are though, you’ll have to throw it out instead…

Vinyl
Vinyl actually isn’t a plastic… or anything at all really. People seem to mistake that Vinyl is a plastic of some sort seen in some Kotobukiya figures. (really old Final Fantasy 8 figures, Star Wars figures, Matrix figures). Most of these Kotobukiya figures are hollow inside, meaning that the figure is constructed out of various hollow tubes put together. In actuality, Vinyl is any compound that includes a “vinyl group” (this gets into chemistry. If you’re interested, look up “Ethylene”). So in essence, PVC is a vinyl. Just that those Kotobukiya figures use a different type of PVC compound that’s a lot softer and thinner, making them highly flexible. “Vinyl Figures” are by far the worst for the environment because of the “softening” additives.

Acrylonitrile butadiene styrene (ABS)
ABS plastic is what your Playstation 1 shell (or other console system plastic shell) is made out of. It’s also what most Gundams are made out of. ABS is much harder, and is typically smooth. You can add texture to it, but it’s typically not a very fine texture. It’s impossible for paint to stick, so it almost always has to be primed first. Also, because of it’s hard nature, it’s impossible to get details that are more than 90 degrees angle, because otherwise the piece will be caught in the mold. That’s why all injection kits edges are always perpendicular. It can be round on the top all the way down to the edge, but it cannot go beyond that 90 degree mark.
ABS is made from a combination of monomers made from propylene, ammonia, butane, and coal. The advantage is that it combines the strength and rigid properties, as well as the rubbery toughness (ABS can bend without snapping). ABS is by far the strongest plastic used for making figurines. So while PVC is soft and rubbery in resilience, ABS is tough and rigid.

Resin (Rosin)
Interestingly enough, resin isn’t really a plastic a all from the technical sense. It’s compound consists of mostly organic ingredients found in plants and trees. What we commonly see in figurines is actually a synthetic resin. This synthetic resin has similar properties to ABS, but it is more brittle. It’s more akin to liquid solidified, almost like soap. The process is similar to epoxy - combining two liquids together to cause a chemical reaction of solidifying. When casting resin, this is essentially what happens. A finished resin cast has the same smoothness as PVC, but has trouble sticking paint. It too has to be primed. Resin is that it’s typically used for hobby kits, and therefore the sculptor doesn’t have to concern too much with technical restrictions of mass production products like PVC and ABS. The pieces are cut up into logical manners to fit within the restriction, and it’s up to the hobbyist to hide the seams, and fit the pieces together. The advantage of resin kits is that it’s soft and easy to sand and cut, while sturdy enough to hold up weight. High quality resin is typically very dense and can withstand quite a bit of pounding, but will shatter under significant pressure, while ABS would simply bounce back. But because of ABS’s toughness, it’s easier to sand resin.


Polystone (Resin compound)
Polystone is a similar property to resin, but is even more brittle! It’s higher quality than resin because of the base materials it uses - mainly it uses minerals such as aluminum hydrate, as opposed to synthetic materials. It’s typically made for mass-produced statues, such as the Final Fantasy 7 polystone cold-casts. From what I can tell, it seems that polystone is the least restrictive. The edges and cuts seem the cleanest, and a fair amount of detail can be put into it. This may be why polystone is the material of choice for mass produced resin cast figures.

Cold Casting (Epoxy)
Cold-Casting is the process of mixing a urethane resin with a metal powder to give the appearance of a shiny metal surface. It can also be used with paint to produce a resin of a certain color. As far as I know, cold casting is quite the opposite of regular casts, which are typically done with moderate temperature plastic molding. I think with cold casting, the liquid resin is already cold, and is freshly mixed. There is a certain amount of time before the mix solidifies into a solid. It’s during this time that the liquid must be poured into the mold. I believe it’s because of this, that you can get such clean lines and smooth surfaces.

Another method I know of for plastic making include heating plastics into solid molds. A solid object is made as a base, and a sheet of plastic is placed on top, and heated. It then melts and conforms to the shape of which it is placed on. The excess is then cut away. This is typically how plastic take-out trays are made. Another is the blow method, where a sheet of plastic is placed into an enclosed mold, heated with hot air. The air blows and expands the plastic to the walls of the mold and is then cooled. This is typically used to make plastic bottles like milk jugs. Vinyl figures can be made using the above manners, though I don’t know how efficient that actually would be.

Hope that covers it, and if I made any mistakes, post away to correct me!



http://radiantdreamer.wordpress.com/2008/0...olystone-oh-my/
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jkno
post Jan 1 2009, 02:31 PM
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Figurine Science: “PVC”, “Polystone”, “Coldcast”, “ABS”, WTF?



I know many readers of this site collect figurines, action figures and other toys but how many of us here actually know anything about the materials, paints, production process or anything beyond how nice it looks?

Spending a couple of hours doing a wee bit of research on the web, I’ve learnt quite a bit that I’m sure many here would care to know. Hence this new series of articles, titled "Figurine Science" that will talk about the lesser known and perhaps more factual aspects of this hobby.

For the inaugural article on FS, I shall explain the commonly used materials and their properties. I’m sure for the non-science/chemistry students, terms like PVC, ABS probably mean just various types of plastic. But what exactly are these and why is ABS used for bases while PVC for the actual figurine?

Before we start, when we talk figurines, everyone bandies about a few terms. "Resin", "PVC", "Polystone", "Coldcast" mainly. And I am not a chemical engineer so any mistaken information here I would gladly correct if someone in the know points out.

What is "Coldcast"?
Basically, no heat is applied when the material is set in the mould. By mixing two types of liquids, a tough plastic compound is formed.

Polystone
Polystone is the common name for Polyethylene, just another plastic. But there are two main types, High and Low Density. High density is used for the figurines. Polystone offers good resistance to moisture, impact, heat, sunlight, cold and has good rigidity. I mean good compared to PVC. Everything here is compared to PVC.
Polystone distorts of about 80 degrees Celsius. It is not that ductile, lighter than water, and can be moulded, machined, and joined together using welding (difficult to glue). It’s a thermoplastic as well, meaning it can be heated and reshaped and cooled. This is easy to mould and rather durable. The higher heat resistance and rigidity also means figurines do not lean or distort, or worse, start degrading in sunlight. But for this added quality, polystone figurines are more expensive than PVC ones and the selection is a lot less.

Unlike PVC which is more ductile, Polystone does BREAK because of the higher rigidity. So shipping overseas is a bit more of a risk for these. Use EMS at all costs.
And yes, it’s also known as polyethene, the plastic bag. So people who have been fooled by the fancy name, please hang your head in shame.

Poly Vinyl Chloride (PVC)
PVC is one of the most common plastics used in the world. It’s quite similar to rubber and the toughness/malleability of PVC is dependant on the plastisers added. More plastisers = more softness, since they straighten out neatly the long macromolecular polymer chains into neat rows. Some figure collectors complain of an oily film after a while and I would think this is due to the plasticisers migrating to the surface of the plastic. Small plasticiser molecules are pretty mobile and after a period of time, they accumulate on the surface to produce a oily crud.

This is also why PVC tends to get a bit crappy and brittle after a long time. Oh yeah these plasticisers are quite toxic too. And if you have a fire at home, dump your figurines at them to extinguish it, since the chlorine produced retards the flame. Btw, some plasticisers are thought to reduce the quality of MAN SPERM.

A very large percentage of the figures sold are made of PVC. From gashapon, trading figures to 1/6s, these are mainly PVCs. Cheap material cost, easy of moulding, ductility (it won’t break much, just bend) are the reasons why it is used.
Never leave them in the sun. Ultraviolet rays produce free radicals on PVC, chlorine free radicals, that combine to form chlorine gas and the material is decomposed. The sun also heats them up and PVC distorts at a temperature of 60 degrees Celsius. Being a thermoplastic, you can actually heat it up and bend it, then cool for it to maintain that shape.

PVC, due to the addition of chlorine atoms which have a pretty high molecular mass compared to C and H, is heavy for a plastic.


ABS (Acrylonitrile Butadiene Styrene)
ABS is commonly used for the bases of figurines. It’s pretty recognisable, just think of LEGO blocks. That’s what they are made of. ABS has good impact strength and is not really flexible but rather stiff. These properties plus the glossy surface make it a suitable material for figurine bases. Interestingly, unlike all the above, ABS is not a compound but just a blend of 3 types of plastic.

"ABS is an amorphous thermoplastic blend. The recipe is 15-35% acrylnitrile, 5-30% butadiene and 40-60% styrene. Depending on the blend different properties can be achieved.

Acrylnitrile contributes with thermal and chemical resistence, and the rubberlike butadiene gives ductility and impact strength. Styrene gives the glossy surface and makes the material easily machinable and less expensive." -Designinsite
ABS is more expensive than PVC and is slightly lighter too. Its price is commonly used as the dividing line between common plastics like PVC and more expensive industrial plastics. ABS has a higher distortion temperature at 75 degrees. Its properties are also easily modified by varying the proportions of its components. Its natural colour is an opaque ivory but dyes can be applied.

http://www.riuva.com/?p=301
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jkno
post Jan 1 2009, 02:32 PM
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Cold Cast Resin (as compared to PVC)

• Greater density resulting in much greater mass
• Better conductor of heat
• Higher opacity
• Smoother surface
• Heatless casting
• Greater strength
• Brittle and less malleable

So now that we know what’s different, what are the effects on the figure?
The resin figure, for an equivalent sized PVC one, weighs about twice as much. This has pros and cons. There is added stability and it feels more like a sculpture than a toy. But the downsides are, increased shipping cost, bulkiness and of course, greater acceleration when falling. Note that I didn’t say leaning.

PVC is a very poor heat conductor compared to resin. While the term cold cast doesn’t have any co-relation to this, the figurine is indeed cold at room temperature due to its good heat conductability, that siphons heat off your hand when touching it.
The higher opacity is an issue. PVC is inherently colourless (though most are dyed), while most resin is a solid colour in its raw form. This effect does produce differences in the final paintwork. Combine this factor with the smooth finish of resin for an even greater difference.

The semi-gloss surfacing of PVC normally used contributes to a more realistic and non-toy appearance, with greater tones. Cold Cast Resin is normally produced and finished to be quite smooth and hence reflective, hence losing a lot of the subtle detail a PVC skintone has.

Resin and PVC are produced differently. PVC tend to have seamlines and inject scars, due to the process of injecting moulding. While I’m not exactly sure of the production process of cold cast, resin figures has significantly less or none of these seam lines and some parts are hollow, like the Rozen Maiden. Resin is also sandable, which allows for the removal of such seam lines and other defects while PVC cannot. Sand rubber? Furthermore, PVC is always solid. PVC parts are also attached through glueing while for CCR, glue is not used. But resin is harder to manipulate when it comes to micro details so resin figures have generally less detail than an equivalent sized PVC figure though the larger general scale of it covers this flaw.

Resin is a lot stronger than PVC. This makes it suitable for large figurines, 1/6 and above. That is why you never see PVC exceed 1/6 scale if they are standing. They don’t lean.

The greater strength but higher brittleness (like ceramics) also makes resin susceptible to breakage either due to accidents or shipping stresses. You can slam PVC figures on the ground and get no harm done but dropping a cold cast figure on the drop would be considered a major heartbreaking event in one’s life.
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